Monitoring Organochlorine Pesticides in Selected River Systems in the Philippines

 

Evangeline C. Santiago

NPC from the Philippines

Natural Sciences Research Institute

University of the Philippines

 

The river systems of two important fish- producing and agricultural provinces in the Philippines were selected as study areas for the second three-year phase (2002-2005) of UNU Monitoring project in the Philippines. The monitoring aims to determine if significant residues of organochlorine pesticides are present in the river waters and sediments that could potentially contaminate the fish produced in the provinces.

 

The first year monitoring in Laguna Rivers detected traces of BHC, aldrin, trans and cis chlordane, dieldrin and DDT and endrin aldehyde in water samples at the levels near the Method Detection Limits during the first sampling and significant levels of dieldrin (0.03-0.13 ppb) during the second sampling.  Aldrin was detected in most Pangasinan Rivers at levels (0.063 ppb) higher than the MDL during the first sampling.  During the second sampling, dieldrin was most significant (0.04-0.09 ppb) in all Pangasinan sites and endrin aldehyde (0.27 ppb) in one river site.

 

The second year monitoring showed only traces of trans and cis chlordane in most river waters from both provinces during the first sampling. Traces of dieldrin, p,pfDDT and trans-nonachlor were detected during the second sampling in addition to the chlordanes. However, the concentrations detected were all below the MDLs.

 

It is extremely difficult to derive conclusions from the monitoring results. The extraction method and the GC/MS method differed for the first and second years. The considerable decrease in the OCPs detected in the second year maybe due to an improvement of the analytical method or maybe due to natural loss of the pesticides with time.